I've recently switched from msn messenger to trillian and I do prefere this. I have read through the manual on trillian's website, but found no help there. I have downloaded a nice skin with no problems, it's only installing it that bugs me.
There doesn't seem to be some handy installing file in the download that just needs to be clicked. The name of the skin in question is Logika, in case that should matter.
Once you have it installed, you would open up your trillian program, click File-->Preferences-->Skins--> and then choose which skin you wnat to use from the drop-down menu,
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